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FextraBot

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Actually they appear with the bonfire ascetic. It was quite a shock when I went for the old witch soul and they came out of walls.

SingularitysMarauder

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I do not confirm for I had played with bonfire ascetic during my first playthrough as a choosen character, and I did not see any pyromancers in that room. I did see them in NG+ though.
These have low health and don't really dodge much. While dispatching them, pay more attention to the Sinner than to them.
If you kill them like 20 times they stop spawning??