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Can an undead use this to poison themselves?
Yes, it poisons through magic armor as well.
Was experimenting with Rain and Contamination on the beach. It turns out that Contamination will only spread poison through so much of a vast water surface before it runs out and further water surface stays water. The same seems to be true of Ignition and a vast poison surface. Not sure yet if the limit is area or radius (though I'd guess radius). For reference, Contamination from the ruined bridge section with the camp site may not spread completely over Dallis and crew at the Fort Joy gate event; that's about the limit.
Changes Ice to Poison as well.
Does this harm your allies as well? I know they will be poisoned but does the initial "deal X amount of poison dmg" hurt them?